In order to prevent a student from accessing a website permanently, you can add a "Permanent Rule" to the student in Net-Ref, so that the student cannot access that page. 


For example, you may want to prevent all access to email for a student. 


We can add a permanent rule for "mail.google.com"


Click the "I" for the student in Net-Ref

Then click "Permanent Rules", then click the "Plus" button



Then enter the URL and a Display Name for the URL which you would like to permanently block.  NOTE: you can also permanently allow using the radio button under "Rule Type"